Thermal degradation and aging behavior of polytriazole polyethylene oxide‐tetrahydrofuran elastomer based on click‐chemistry

Abstract

Polytriazole polyethylene oxide‐tetrahydrofuran (PTPET) elastomer was prepared based on the click‐chemistry reaction between the CCH and N3 groups. The PTPET exhibits improved thermal stability with an activation energy of 204 kJ/mol compared with hydroxyl‐terminated polyethylene oxide‐tetrahydrofuran (PET) elastomer. TG‐FTIR and pyrolysis‐gas chromatography–mass spectrometry (Py‐GC–MS) were used to analyze the pyrolysis mechanism and products of the PTPET elastomer. The pyrolytic mechanism of PTPET mainly involves breakage of the polyether chains. The main pyrolytic products were identified. The PTPET underwent for 180 days at 50°C and 60°C. The tensile properties, dynamic mechanical analysis (DMA) and TGA of the aged PTPET were investigated. The tensile stress and strain of the aged PTPET increased until 120 days (at 60°C) or 150 days (at 50°C), which could be attributed to the postcuring of the elastomer. The scission of the PTPET chains due to aging could dominate after aging for 120 days (at 60°C) or for 150 days (at 50°C), resulting in the reduction of mechanical properties.

Curing Behaviors of Alkynyl-Terminated Copolyether with Glycidyl Azide Polymer in Energetic Plasticizers

“…The PTPET elastomer was synthesized by the click-chemistry reaction between ATPET and GAP (M n = 427 g/mol) in the presence of a copper catalyst at 50 • C for 7 days. A schematic diagram of the synthesis method for the PTPET elastomer is shown in Scheme 1 [13]. Scheme 1.…”

“…[10,11] Polytriazole polyethylene oxide−tetrahydrofuran (PTPET) elastomer is an example of a propellant successfully assembled by click chemistry in. [12,13] This elastomer is prepared from alkyne-terminated polyethylene oxide tetrahydrofuran co-polyether (ATPET) and glycidyl azide polymer (GAP). It has the potential to be used in NEPE propellants.…”