1991
DOI: 10.1016/0040-6031(91)87247-t
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Thermal decomposition of wood in oxidizing atmosphere. A kinetic study from non-isothermal TG experiments

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Cited by 36 publications
(17 citation statements)
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“…The kinetic parameters, E a and A , at the second stages of CEB10 and CEB12 resulted to be 15.748 kJ/mol and 1.35E+03 min −1 , 20.044 kJ/mol and 3.91E+03 min −1 , respectively. The two activation energies were in good agreement with literature data of lignin decomposition 25, 26. This result confirmed that devolatilization and degradation of pyrolytic lignin in the CEBs occurred in the second mass loss step.…”
Section: Resultssupporting
confidence: 90%
“…The kinetic parameters, E a and A , at the second stages of CEB10 and CEB12 resulted to be 15.748 kJ/mol and 1.35E+03 min −1 , 20.044 kJ/mol and 3.91E+03 min −1 , respectively. The two activation energies were in good agreement with literature data of lignin decomposition 25, 26. This result confirmed that devolatilization and degradation of pyrolytic lignin in the CEBs occurred in the second mass loss step.…”
Section: Resultssupporting
confidence: 90%
“…In many articles, kinetic parameters of the decomposition process of lignocellulosic materials have been estimated, assuming two global reactions with n th‐order rates. For the oxidative decomposition step, the activation energies are roughly comprised between 101 and 136,25 13026, 83–93,34 78 or 12135 (two computation methods), and 52–99 27. For the char oxidation step, the values reported are 35–65,25 110,26 65–83,34100 or 128,35 87–202,27 and 94 kJ/mol 36.…”
Section: Resultsmentioning
confidence: 99%
“…In general, DTG curves obtained from the thermal degradation of wood in an inert atmosphere do not yield a peak due to the thermal degradation of lignin. In contrast, DTG curves obtained from the thermal degradation of wood in an oxygen environment generally yield a peak due to the thermal degradation of lignin (Chauvette et al, 1985;Cordero et al, 1991;Orfao et al, 1999;Fang et al, 2006;Emandi et al, 2011;Niu et al, 2011).…”
Section: Solubility Of Heartwood Of L Orientalismentioning
confidence: 99%