Thermal decomposition of triacetone triperoxide by differential scanning calorimetry

Shiue, Gong-Yih; Huang, An‐Chi; Chen, Jiann-Rong

doi:10.1007/s10973-018-7021-5

Cited by 15 publications

(1 citation statement)

References 17 publications

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“…An integral kinetic model named FWO model was devised, and the formula is presented in Eq. ( 11 ) 48 , 49 : where G ( α ) is the integral form to the kinetic mechanism function 46 .…”

Section: Experiments and Methodsmentioning

confidence: 99%

Thermal hazard evaluation on spontaneous combustion characteristics of nitrocellulose solution under different atmospheric conditions

Zhi-ping

Jiang

Huang

et al. 2021

Sci Rep

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Nitrocellulose (NC) is widely used in both military and civilian fields. Because of its high chemical sensitivity and low decomposition temperature, NC is prone to spontaneous combustion. Due to the dangerous properties of NC, it is often dissolved in other organic solvents, then stored and transported in the form of a solution. Therefore, this paper took NC solutions (NC-S) with different concentrations as research objects. Under different atmospheric conditions, a series of thermal analysis experiments and different reaction kinetic methods investigated the influence of solution concentration and oxygen concentration on NC-S’s thermal stability. The variation rules of NC-S’s thermodynamic parameters with solution and oxygen concentrations were explored. On this basis, the spontaneous combustion characteristics of NC-S under actual industrial conditions were summarized to put forward the theoretical guidance for the spontaneous combustion treatment together with the safety in production, transportation, and storage.

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“…An integral kinetic model named FWO model was devised, and the formula is presented in Eq. ( 11 ) 48 , 49 : where G ( α ) is the integral form to the kinetic mechanism function 46 .…”

Section: Experiments and Methodsmentioning

confidence: 99%

Thermal hazard evaluation on spontaneous combustion characteristics of nitrocellulose solution under different atmospheric conditions

Zhi-ping

Jiang

Huang

et al. 2021

Sci Rep

Self Cite

View full text Add to dashboard Cite

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Evaluating the thermal stability of chemicals and systems: A review

Andriani,

Pio,

Salzano

et al. 2024

Can J Chem Eng

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In the realm of chemical processing, particularly at the industrial scale, safety is of utmost importance. A predominant factor causing accidents within the chemical industry is runaway phenomena, primarily initiated by uncontrolled exothermic reactions. This review critically examines the often‐overlooked decomposition mechanisms as a significant contributor to thermal energy release, necessitating a comprehensive revision and understanding of both experimental and theoretical strategies for assessing thermal degradation. Key to this discourse is the explication of calorimetry as the principal experimental technique, alongside ab initio quantum chemistry simulations as a robust theoretical framework for quantifying the most relevant properties. However, more than mere cognisance of these methodologies is required for a meticulous thermal stability assessment. The review emphasizes identifying and quantifying fundamental parameters through experimental and theoretical investigations. Only upon acquiring these parameters, including kinetic, thermodynamic, onset, and peak characteristics of the exothermic decomposition reactions, can one effectively mitigate risks and hazards in designing and optimizing chemical processes and apparatus. Furthermore, this review delineates qualitative and quantitative methodologies for hazard assessment, proffering strategies for estimating safe operational conditions and sizing relief devices. The paper culminates in exploring future trajectories in thermal stability assessments, focusing on emerging applications in lithium‐ion batteries, electrolyzers, electrified reactors, ionic liquids, artificial intelligence and machine learning approaches. Thus, the paper underlines the evolving landscape of thermal risk management in contemporary and future chemical industries.

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Study of triplet kinetic of thermal decomposition reaction and sensitivity to impact and electrostatic discharge of HMX polymorphs

Pouretedal

Damiri

Sharifi

2019

J Therm Anal Calorim

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Thermal decomposition of triacetone triperoxide by differential scanning calorimetry

Cited by 15 publications

References 17 publications

Thermal hazard evaluation on spontaneous combustion characteristics of nitrocellulose solution under different atmospheric conditions

Thermal hazard evaluation on spontaneous combustion characteristics of nitrocellulose solution under different atmospheric conditions

Evaluating the thermal stability of chemicals and systems: A review

Study of triplet kinetic of thermal decomposition reaction and sensitivity to impact and electrostatic discharge of HMX polymorphs

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