Abstract:The thermal decompositions of dicitratoborates MI[B(CtHtO7),].nH20 (n=0-2, M' = Rb, K, Li, Nit,,) and MUlB(CtHtO7)z]z .8H20 (M II = Co, Ni, Mn, Cu, Zn, Cd) were investigated by means of TG, DTA and DTG methods. It was found that these thermal decompositions involve three successive stages: dehydration, the endothermal decomposition of the ligand, and oxidation of the residual ~ganic component. The volatile products of decomposition in each stage were detected by means of gas chromatography. The method of TGcur… Show more
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