Thermal Decomposition of Copper (II) Dicalcium (II) Formate

New double formates Na3M(HCOO)6 (M=Ga, In) with diamond-like metal framework: Synthesis, structure and coordination modes

“…One could also expect more diversified structure frameworks when the compounds contain different cations with different valence and/or coordination number. In fact, double formates, such as MM 0 (HCOO) 4 [27][28][29][30][31][32], M 2 M 0 (HCOO) 6 [27,30,[33][34][35], MM'(HCOO) 4 (H 2 O) 2 (M = Ca, Sr, and Ba, M 0 = Cu) [36], Ba 2 M(H-COO) 6 (H 2 O) 4 (M = Fe, Co, Ni, Cu, Zn) [37][38][39][40][41] and M x M 0 1Àx (HCOO) 2 Á2H 2 O (M = Mn, Co, Ni, Zn, Cd, Mg, and M 0 = Cu) [42][43][44][45][46], were known for many years. In the structure of SrCu(H-COO) 4 (H 2 O) 2 , for example, four different connection modes, 2.20, 2.11, 3.21 and 4.22 coexist.…”