“…In a high-temperature environment, oxygen reacts with Al, Co, and Ni in the metal bond coat, causing a change at the interface and internal oxidation. The increase in the oxidation degree leads to the formation and evolution of Al 2 O 3, layering of TGO (with α- Al2O 3 and Cr 2 O 3 ), formation of spinel phases (Ni(Al, Cr) 2 O 4 and NiO), and precipitation of elemental metallic phases (γ-Ni, α-Cr, γ-Al, β-Ti) 8 .…”