Ashes produced by the combustion of two types of biomass wastesone generated during the extraction of olive oil (olive pomace) and the other during rice-huskingswere used, without any prior treatment, to make insulating plates with fire-resistant properties by means of simple molding and curing methods. The plates, with a weight composition of 69% olive-pomace ash, 1% rice-husk ash, 29% gypsum, and 1% glass fiber, present a great capacity for water retention and, consequently, when subjected to different thermal tests, showed excellent insulating properties. Furthermore, they also demonstrated acceptable mechanical properties with regard to compressive and bending strengths and resistance to impact, as well as a minimal environmental impact. The plates developed with a high biomass-ash ratio could potentially be useful as components of construction materials used for passive fire protection, such as doors and firewalls in buildings and industrial installations.