2010
DOI: 10.1111/j.1551-2916.2010.03722.x
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Thermal and Structural Property Characterization of Commercially Moldable Glasses

Abstract: In this paper, we report the development of a kinetic model for precisely predicting glass material property response to a defined molding profile. The glass viscosity, thermal expansion, and specific heat properties for two commercial optical glasses, P‐SK57 and L‐BAL35 were measured and are reported in this paper. These data were used with the Tool–Narayanaswamy–Moynihan (TNM) model for glass structural relaxation in order to develop a thermal expansion model that simulates the glass workpiece changes throug… Show more

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Cited by 24 publications
(22 citation statements)
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“…this cte difference means that the chalcogenide will contract a greater volume during the cool down period than an oxide glass would, and compensations for this change in volume need to be built into the mold geometry. Low thermal conductivity and steep viscosity curve for chalcogenide glasses bring another layer of difficulty, which make precise control of the temperature of the molding system and the glass critical to achieving good parts [31][32][33][34]. Thus, to efficiently determine an optimized thermal cycle for a new candidate optical design (component material and shape), it is necessary to employ computational techniques which include contributions due to these various properties along with relaxation properties (structural and stress).…”
Section: © Woodhead Publishing Limited 2014mentioning
confidence: 99%
“…this cte difference means that the chalcogenide will contract a greater volume during the cool down period than an oxide glass would, and compensations for this change in volume need to be built into the mold geometry. Low thermal conductivity and steep viscosity curve for chalcogenide glasses bring another layer of difficulty, which make precise control of the temperature of the molding system and the glass critical to achieving good parts [31][32][33][34]. Thus, to efficiently determine an optimized thermal cycle for a new candidate optical design (component material and shape), it is necessary to employ computational techniques which include contributions due to these various properties along with relaxation properties (structural and stress).…”
Section: © Woodhead Publishing Limited 2014mentioning
confidence: 99%
“…More details on the experimental techniques, their drawbacks and methods of extraction of parameters are discussed in Gaylord et al [28]. The TNM-model parameters based on DSC measurements have to be converted to a form that is acceptable by the finite element code.…”
Section: Structural Relaxation Implementationmentioning
confidence: 99%
“…The parameters required for the Tool-Narayanaswamy-Moynihan (TNM) model to capture the structural relaxation in P-SK57 TM glass are experimentally characterized and reported in Ref. 31 for glass. The parameters to evaluate fictive temperature are specified in the form of Kohlrausch-Williams-Watts function which it is converted into equivalent Prony series for which w i and s vi (Equation A.5) are evaluated as 8…”
Section: Characterization Of Thermo-mechanical Properties Of P-sk57 Tmentioning
confidence: 99%