2019
DOI: 10.1016/j.jlumin.2018.09.046
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Thermal and spectroscopic properties studies of Er3+-doped and Er3+/Yb3+-codoped niobium germanate glasses for optical applications

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Cited by 30 publications
(11 citation statements)
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“…4(b) shows that FWHM of 4 I 13/2 / 4 I 15/2 emission band increases gradually from 59 to 74 nm when Er 2 O 3 concentration varies from 0.5 to 3 mol%. These values are larger than that in other glass hosts used for optical ber ampliers, such as 38 nm in lead borosilicate glasses, 28 47 nm in lead phosphate glasses, 29 46 nm in niobium germanate glasses 30 and 48 nm in uorotellurite glasses. 5 The larger FWHM is ascribed to not only high refractive index ($2.1) which strengthens the ligand elds around Er 3+ but also to the existence of multiple structural units such as TeO 4 trigonal bipyramid, TeO 3 trigonal pyramid, TeO 3+1 polyhedra, WO 6 octahedra and WO 4 tetrahedra, which creates diverse coordination environments.…”
Section: Fluorescence Spectra Lifetime and Energy Transfer Mechanismmentioning
confidence: 69%
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“…4(b) shows that FWHM of 4 I 13/2 / 4 I 15/2 emission band increases gradually from 59 to 74 nm when Er 2 O 3 concentration varies from 0.5 to 3 mol%. These values are larger than that in other glass hosts used for optical ber ampliers, such as 38 nm in lead borosilicate glasses, 28 47 nm in lead phosphate glasses, 29 46 nm in niobium germanate glasses 30 and 48 nm in uorotellurite glasses. 5 The larger FWHM is ascribed to not only high refractive index ($2.1) which strengthens the ligand elds around Er 3+ but also to the existence of multiple structural units such as TeO 4 trigonal bipyramid, TeO 3 trigonal pyramid, TeO 3+1 polyhedra, WO 6 octahedra and WO 4 tetrahedra, which creates diverse coordination environments.…”
Section: Fluorescence Spectra Lifetime and Energy Transfer Mechanismmentioning
confidence: 69%
“…It is worth noting that the maximum gain coefficient of TWYE-1 glass is 4.07 cm −1 at 1534 nm, which is larger than those values reported in borosilicate glass (1.01 cm −1 ), 22 phosphate glasses (1.02 cm −1 ), 36 bismuthate glass (3.51 cm −1 ) 33 and niobium germanate glass (0.28 cm −1 ). 30 …”
Section: Resultsmentioning
confidence: 99%
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“…The insertion of transition metal oxides can improve these properties, as reported in niobium, zinc, tungsten, and molybdenum phosphate glasses. In addition, it can result in a significant decrease in the phonon energy, minimizing the nonradiative processes when doped with rare‐earth ions (RE) . RE‐doped glasses are attractive for optical applications such as lasers and telecommunications devices …”
Section: Introductionmentioning
confidence: 99%
“…In addition, it can result in a significant decrease in the phonon energy, 10 minimizing the nonradiative processes when doped with rare-earth ions (RE). 11,12 RE-doped glasses are attractive for optical applications such as lasers 13 and telecommunications devices. 14,15 Recently, structural changes in phosphate glasses has been reported by the addition of WO 3 , 16,17 Ta 2 O 5 , 18,19 V 2 O 5 , 20 TiO 2 , [21][22][23] and Nb 2 O 5 1,5,24 .…”
mentioning
confidence: 99%