“…Again, high temperatures for curing, such as above 200 C, should be avoided because of potential degradation of some active substances. In this regard, a small molecule, namely 1,3,5-tris (azidomethyl)benzene (TAMB), was prepared by Pötzsch and Voit [233] and successfully used to crosslink the hb-PPh matrix both thermally and photochemically. The mechanisms of these two crosslinking reactions were different; in thermal curing, triazole units were formed between the acetylene groups of hb-PPh and the azide group of the crosslinker in a 1,3-dipolar cycloaddition reaction.…”