2008
DOI: 10.1016/j.jpowsour.2008.03.072
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Thermal and mechanical properties of LaCoO3 and La0.8Ca0.2CoO3 perovskites

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Cited by 41 publications
(35 citation statements)
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“…In this way, Fossdal et al and Orlovskaya et al have shown that LaFeO 3 , 35 LaCoO 3 and La 0.8 Ca 0.2 CoO 3 perovskites 36,37 present a ferroelastic behaviour with orthorhombic-rhombohedral phase transition. Besides, Young's modulus evolution of LSFG8273 and LSF821 perovskites with temperature between 25 • C and 600 • C is similar to Young's modulus evolution of LaCoO 3 perovskites presented by Orlovskaya et al 36,37 The ferroelastic behaviour of LSFG8273 and LSF821 perovskites could be expected above the orthorhombic-to-rhombohedral phase transition described in this study by analogy with LaCoO 3 and La 0.8 Ca 0.2 CoO 3 perovskites. However, this ferroelastic behaviour does not explain clearly the increase of Young's modulus with temperature between 400 • C and 600 • C, and leads to a nonlinear stress-strain relationship which should be confirmed by a complementary microstructural analysis and mechanical tests in further studies, such as bending or compressive tests.…”
Section: Young's Modulussupporting
confidence: 88%
“…In this way, Fossdal et al and Orlovskaya et al have shown that LaFeO 3 , 35 LaCoO 3 and La 0.8 Ca 0.2 CoO 3 perovskites 36,37 present a ferroelastic behaviour with orthorhombic-rhombohedral phase transition. Besides, Young's modulus evolution of LSFG8273 and LSF821 perovskites with temperature between 25 • C and 600 • C is similar to Young's modulus evolution of LaCoO 3 perovskites presented by Orlovskaya et al 36,37 The ferroelastic behaviour of LSFG8273 and LSF821 perovskites could be expected above the orthorhombic-to-rhombohedral phase transition described in this study by analogy with LaCoO 3 and La 0.8 Ca 0.2 CoO 3 perovskites. However, this ferroelastic behaviour does not explain clearly the increase of Young's modulus with temperature between 400 • C and 600 • C, and leads to a nonlinear stress-strain relationship which should be confirmed by a complementary microstructural analysis and mechanical tests in further studies, such as bending or compressive tests.…”
Section: Young's Modulussupporting
confidence: 88%
“…The thermal expansion coefficients obtained for the SrCo 1−x Sb x O 3−ı system (Table 1) are considerably high for SOFC applications but they are in the range of those presented by other Co-containing perovskite like materials [19][20][21].…”
Section: Thermal Expansion Measurementsmentioning
confidence: 85%
“…3,[6][7][8] Despite numerous studies on electrochemical properties, there are few investigations on mechanical properties. [9][10][11][12][13][14][15] The mechanical properties such as elastic modulus and fracture properties have been investigated by means of resonance method and * Corresponding author. Tel.…”
Section: Introductionmentioning
confidence: 99%