Thermal and ignition properties of hexanitrostilbene (HNS) microspheres prepared by droplet microfluidics

Han, Ruishan; Lu, Feipeng; Zhang, Fang; Wang, Yan-lan; Zhou, Mi; Qin, Guosheng; Chen, Jianhua; Wang, Haifu; Chu, Enyi

doi:10.1016/j.dt.2022.05.006

Cited by 12 publications

(1 citation statement)

References 40 publications

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“…In the civil field, heat-resistant explosive is mainly used in the perforating blasting equipment of oil and gas wells. 2,2′,4,4′,6,6′-hexanitrostilbene (HNS) [ 3 , 4 , 5 , 6 , 7 ], tetranitro-2,3,5,6-dibenzo-1,3a,4,6a-tetraazapentalene (TACOT) [ 8 , 9 , 10 , 11 ], 2,2′,2″,4,4′,4″,6,6′,6″-nonanitroterphenyl (NONA) [ 12 , 13 ], 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) [ 14 , 15 , 16 , 17 , 18 , 19 ], and 2,6-bis(picrylamino)-3,5-dinitropyridine (PYX) [ 20 , 21 , 22 , 23 , 24 , 25 ] are commonly used in heat-resistant explosives. The energy level of TACOT is low and the synthesis steps are complex.…”

Section: Introductionmentioning

confidence: 99%

Facile Recrystallization Process for Tuning the Crystal Morphology and Thermal Safety of Industrial Grade PYX

Zhang

Ren

et al. 2023

Molecules

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In this study, the crystal appearance of industrial grade 2,6-diamino-3,5-dinitropyridine (PYX) was mostly needle-shaped or rod-shaped with an average aspect ratio of 3.47 and roundness of 0.47. According to national military standards, the explosion percentage of impact sensitivity s about 40% and friction sensitivity is about 60%. To improve loading density and pressing safety, the solvent–antisolvent method was used to optimize the crystal morphology, i.e., to reduce the aspect ratio and increase the roundness value. Firstly, the solubility of PYX in DMSO, DMF, and NMP was measured by the static differential weight method, and the solubility model was established. The results showed that the Apelblat equation and Van’t Hoff equation could be used to clarify the temperature dependence of PYX solubility in a single solvent. Scanning electron microscopy (SEM) was used to characterize the morphology of the recrystallized samples. After recrystallization, the aspect ratio of the samples decreased from 3.47 to 1.19, and roundness increased from 0.47 to 0.86. The morphology was greatly improved, and the particle size decreased. The structures before and after recrystallization were characterized by infrared spectroscopy (IR). The results showed that no chemical structure changes occurred during recrystallization, and the chemical purity was improved by 0.7%. According to the GJB-772A-97 explosion probability method, the mechanical sensitivity of explosives was characterized. After recrystallization, the impact sensitivity of explosives was significantly reduced from 40% to 12%. A differential scanning calorimeter (DSC) was used to study the thermal decomposition. The thermal decomposition temperature peak of the sample after recrystallization was 5 °C higher than that of the raw PYX. The thermal decomposition kinetic parameters of the samples were calculated by AKTS software, and the thermal decomposition process under isothermal conditions was predicted. The results showed that the activation energy (E) of the samples after recrystallization was higher by 37.9~527.6 kJ/mol than raw PYX, so the thermal stability and safety of the recrystallized samples were improved.

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