1987
DOI: 10.1007/bf01913969
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Thermal analysis in studies of photochemical transformations in PVC

Abstract: The effects of photochemical processes in PVC in response to UV irradiation at 253.7 nm on its thermal stability were investigated. It was found that small differences in the efficiency of the photochemical processes taking place in the PVC can be recorded in the thermal measurements, and that photodehydrochlorination lowers the temperature of thermal dehydrochlorination, while photooxidation and crosslinking increase the temperature of complete decomposition of this polymer.

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Cited by 4 publications
(1 citation statement)
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“…PVC stretch and shrink films are used for packaging fresh foods such as red meat, poultry, fruits and vegetables for supermarkets and domestic use in China. However, with UV irradiation the bonds between plasticizers and polymers may be disrupted [6,7] and more plasticizers might migrate into the food packaged. It is well documented that plasticizers such as phthalates and adipates from plasticized films readily migrate into fatty foods when being heated by microwave or other heating method [8,9,10].…”
Section: Introductionmentioning
confidence: 99%
“…PVC stretch and shrink films are used for packaging fresh foods such as red meat, poultry, fruits and vegetables for supermarkets and domestic use in China. However, with UV irradiation the bonds between plasticizers and polymers may be disrupted [6,7] and more plasticizers might migrate into the food packaged. It is well documented that plasticizers such as phthalates and adipates from plasticized films readily migrate into fatty foods when being heated by microwave or other heating method [8,9,10].…”
Section: Introductionmentioning
confidence: 99%