A 0/1-simplex is the convex hull of n + 1 affinely independent vertices of the unit n-cube I n . It is nonobtuse if none its dihedral angles is obtuse, and acute if additionally none of them is right. Acute 0/1-simplices in I n can be represented by 0/1-matrices P of size n × n whose Gramians G = P ⊤ P have an inverse that is strictly diagonally dominant, with negative off-diagonal entries.In this paper, we will prove that the positive part D of the transposed inverse P −⊤ of P is doubly stochastic and has the same support as P . In fact, P has a fully indecomposable doubly stochastic pattern. The negative part C of P −⊤ is strictly row-substochastic and its support is complementary to that of D, showing that P −⊤ = D − C has no zero entries and has positive row sums. As a consequence, for each facet F of an acute 0/1-facet S there exists at most one other acute 0/1-simplexŜ in I n having F as a facet. We callŜ the acute neighbor of S at F .If P represents a 0/1-simplex that is merely nonobtuse, the inverse of G = P ⊤ P is only weakly diagonally dominant and has nonpositive off-diagonal entries. Consequently, P −⊤ can have entries equal to zero. We show that its positive part D is still doubly stochastic, but its support may be strictly contained in the support of P . This allows P to have no doubly stochastic pattern and to be partly decomposable. In theory, this might cause a nonobtuse 0/1-simplex S to have several nonobtuse neighborsŜ at each of its facets.In the remainder of the paper, we study nonobtuse 0/1-simplices S having a partly decomposable matrix representation P . We prove that if S has such a matrix representation, it also has a block diagonal matrix representation with at least two diagonal blocks. Moreover, all matrix representations of S will then be partly decomposable. This proves that the combinatorial property of having a fully indecomposable matrix representation with doubly stochastic pattern is a geometrical property of a subclass of nonobtuse 0/1-simplices, invariant under all n-cube symmetries. We will show that a nonobtuse simplex with partly decomposable matrix representation can be split in mutually orthogonal simplicial facets whose dimensions add up to n, and in which each facet has a fully indecomposable matrix representation. Using this insight, we are able to extend the one neighbor theorem for acute simplices to a larger class of nonobtuse simplices.