The structure of 20 Na below the proton threshold energy of 2190.1(11) keV [1] is firmly established and the analog partner levels in the mirror nucleus 20 F have been identified [2]. The situation is not so clear for the region above the proton threshold. This region has attracted particular interest for some decades because the reaction sequence 15 O(α,γ ) 19 Ne(p,γ ) 20 Na is thought to represent the main breakout route between the hot CNO cycles and the rp process in x-ray bursters [3]. The purpose of the present Brief Report is to consider the level structure of 20 Na above the proton threshold and its relationship to known levels in 20 F [4], shown in Fig. 1.The most recent study of levels above the proton threshold of 20 Na was that of Wallace et al. [5] from measurements of the β-delayed proton decay of 20 Mg. That paper focused on a search for a weak proton decay branch of the key astrophysical resonance for the 19 Ne(p,γ ) 20 Na reaction at ∼450 keV. For a detailed discussion of previous studies of the attempt to identify the spin-parity of this resonance, and to determine its strength, readers are referred to Ref.[5] as a starting point. Here we note that it was concluded that the resonance had J π = 3 + and corresponded to a known 3 + level at 2966 keV in the mirror nucleus 20 F [5]. The relatively large Coulomb energy difference has been attributed to a significant percentage of the wave function containing a 2s 1/2 nucleon component [6]. An analysis was presented in Ref.[5] that combined the new high-precision proton threshold energy measurement of Ref.[1] with a precise relative energy difference measurement between this state and a neighboring 1 + resonance obtained in a high-resolution study of the 20 Ne( 3 He,t) 20 Na charge exchange reaction [7]. That information was used to derive a new more precise proton resonance energy of 457(3) keV and an excitation energy of 2647(3) keV in 20 Na. The following discussion takes the above assignment from Ref.[5] and explores the level structure above this excitation energy in relation to the known mirror level structure in 20 F.Resonances in p + 19 Ne scattering studies were identified at precise energies of 797(2) and 887(2) keV with respective 1 + and 0 + assignments by Coszach et al. [8]. Transitions to both states were seen in the recent β-delayed proton decay study of 20 Mg [5]. Using the new proton threshold energy measurement [1] excitation energies of 2987(2) and 3077(2) keV have been derived [5]. These resonances have been paired in shell model studies with states at 3488 (1 + ) and 3526 (0 + ) keV in 20 F, with again the relatively large Coulomb energy differences being associated with large 2s 1/2 components [6,9]. It is important to note that in Table 3 of the β-delayed proton decay study of 20 Mg presented by Piechaczek et al.[10] an excitation energy of 3001(2) keV is quoted for the 1 + resonance, which was subsequently reproduced in the compilation of Tilley et al. [4]. However, the energy in that table is derived from a 1 + resonance energy...