The paper considers the hierarchic concept of structural levels in inorganic materials. On the one hand, it reflects the hierarchic structure of matter and, on the other hand, plays a significant part in the well-known materials-science triad: chemical composition-structure-properties. It is the hierarchic concept of structure that may underlie the structural engineering of materials. Special significance of the concept in nanostructured materials science is emphasized.Inorganic materials have certain chemical composition and structure, which determine their properties needed to perform a specific function.The structure of a material qualitatively characterizes the mutual arrangement and interrelation of its components⎯structural elements. Depending on scale, each material has different structural levels that form a sequence or hierarchy.As applied to inorganic materials, the hierarchy of structural levels should be considered a particular case of the hierarchy of the structural levels of matter as a whole. This aspect was most fully and clearly treated by Weisskopf [1] in describing the so-called quantum ladder in the structure of matter. The quantum ladder is a sequence of structural states of matter occurring as its energy is gradually increased (or decreased).Atoms with fixed internal structure, which can exchange only kinetic energy during elastic collisions, can be selected as the ground state of matter. At higher energies, atoms will be ionized and split into electrons and nuclei. Up to certain energies, the nuclei will remain integral and indivisible but will disintegrate into protons and neutrons with further increase in external energy. Matter will become an unstructured mixture of elementary particles. Each rung of the quantum ladder is associated with a threshold of energy that disturbs the stability of the structure; the smaller the linear scale, the higher the threshold (Table 1).Moving down the quantum ladder from the ground state toward lower energies and, hence, a larger scale, we will see atoms combine into molecules or crystals with specific internal structure. The larger the molecules, the