Theoretical Studies on the Deformation Potential, Electron-Phonon Coupling, and Carrier Transports of Layered Systems

Abstract

The electronic structures, deformation potential, electron-phonon couplings (EPCs), and intrinsic charge transport of layered systemsthe sp + sp 2 hybridized carbon allotropes, graphynes (GYs) and graphdiynes (GDYs), as well as sp 2 + sp 3 hybridized structure with buckling, such as staninehave been investigated theoretically. Computational studies showed that, similar to graphene, some GYs can possess Dirac cones (such as α-, β-, and 6,6,12-GYs), and that the electronic properties of GYs and GDYs can be tuned by cutting into nanoribbons with different widths and edge morphologies. Focusing on the features of Dirac cones, band structure engineering can provide a clue for tuning electronic transport in 2D carbon-based materials. Based on the Boltzmann transport equation and the deformation potential approximation (DPA), the charge carrier mobilities in GYs and GDYs were predicted to be as high as 10 4 -10 5 cm 2 •V −1 •s −1 at room temperature. Interestingly, due to lower EPC strength and longer relaxation time, the charge carrier mobility in 6,6,12-GY with double Dirac cones structure was found to be even larger than that of graphene at room temperature. The unique electronic properties and high mobilities of GYs and GDYs make them highly promising candidates for applications in next generation nanoelectronics. Additionally, through the full evaluation of the EPC by density functional perturbation theory (DFPT) and Wannier interpolation, the EPCs with different phonon branches and wave-vectors as well as charge carrier mobilities for graphene, GYs and stanene have been discussed. This showed that the longitudinal acoustic (LA) phonon scattering in the long wavelength limit is the main scattering mechanism for GYs and graphene, and thus the DPA is applicable. Due to stronger LA phonon scattering, the electron mobilities (∼10 4 cm 2 •V −1 •s −1 ) of α-GYs and γ-GYs were predicted to be one order of magnitude smaller than that of graphene at room temperature by full evaluation of the EPC. However, the DPA would fail if there was buckling in the honeycomb structure and the planar symmetry was broken (absence of σh), such as in stanene, where the inter-valley scatterings from the out-of-plane acoustic (ZA) and transverse acoustic (TA) phonons dominate the carrier transport process and limit the electron mobilities to be (2-3) × 10 3 cm 2 •V −1 •s −1 at room temperature. In addition to our calculations, others have also found that the main scattering mechanisms in layered systems with buckling, such as silicene and germanene, are ZA and TA phonons. Thus, these results give us new insights into the role of EPCs and the limitation of the DPA for carrier transport in layered systems. They also indicate that the carrier mobilities of systems without σh-symmetry can be improved by suppressing the out-of-plane vibrations, for example by clamping by a substrate.

Theoretical Study on Carrier Mobility of Hydrogenated Graphene/Hexagonal Boron-Nitride Heterobilayer

“…Generally speaking, hydrogenation dramatically reduces the mobility of graphene. The theoretical mobility of graphene (3.2 × 10 5 cm 2 /(V s)[ 28 ]) is several orders of magnitude higher than that of HG. In addition, HGs have asymmetric (μ e ≠ μ h ) and anisotropic ( μ (ΓM) ≠ μ (ΓK)) mobilities.…”

“…It should be emphasized that the DPA method may overestimate the mobilities of arsenene, antimonene [ 26 ], and silicene [ 27 ] because it does not consider the effect of flexural acoustic (ZA) phonons. Shuai et al [ 28 , 29 ] discussed the applicability of DPA and found that it can estimate the electronic properties of graphene and graphyne well. The ZA phonons play a minor role in electron-phonon interactions for two-dimensional carbon materials.…”

“…The ZA phonons play a minor role in electron-phonon interactions for two-dimensional carbon materials. The electronic mobility of graphene [ 28 ] at room temperature is estimated to be 3.4 × 10 5 cm 2 /(V s) by DPA method and 3.2 × 10 5 cm 2 /(V s) [ 28 ] by considering all the electron-phonon interactions. As for HG, we will reanalyze the effect of ZA phonons in the next part.…”

Theory, preparation, properties and catalysis application in 2D graphynes-based materials

“…It has relatively many carbon chemical bonds, a great conjugated system, and prominent chemical properties. In addition, GDY has great potential in the field of electronics and energy 35,47,[157][158][159][160][161][162][163][164][165][166][167][168] . In summary, GDR materials are excellent catalyst, energy and sensor materials.…”

Symmetry-Dependent Transport Properties of <i>γ</i>-Graphyne-based Molecular Magnetic Tunnel Junctions

“…Based on the discovery of graphene, two-dimensional (2D) carbon allotropes have attracted wide attention, especially 2D graphyne [18][19][20][21][22] . Unlike graphene, graphyne has both sp and sp 2 hybrid carbon bonds 23,24 . The sp hybrid carbon bonds destroy the original honeycomb lattice of graphene, resulting in four different geometries of graphyne: α-graphyne, β-graphyne, γgraphyne and 6,6,12-graphyne 25,26 .…”