Abstract:The overall rate constant for H‐abstraction (kH) from CH3CH2CH2Cl and D‐abstraction (kD) from CD3CH2CD2Cl by chlorine atoms is described by the formulas:
kH=false(6.48−1.19+1.45false)×10−12·(T298)(1.810.28em±0.28em0.15)·exp(597±0.28em62)Tcnormalm3moleculnormale−1normals−1and kD=false(1.45−0.27+0.33false)×10−12·exp(801±62)Tcnormalm3moleculnormale−1normals−1, respectively. The results of the experiment show that the value of the kinetic isotope effect (kH/kD) for the overall rate constants is also temperature d… Show more
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