Abstract:In this work, we present theoretical results in cyclic staircase voltammetry of a surface catalytic mechanism that features reversible chemical step, the so-called "surface catalytic EC rev ' mechanism". We consider specific surface regenerative mechanism, in which both of the electro-inactive substrates are present in large excess in electrochemical cell from the beginning of the experiment. The chemical reversibility brings at this mechanism more complexity in respect to the features of wellelaborated surfac… Show more
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