1948
DOI: 10.1080/19447014808663155
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The Visco-Elastic Properties of Wool Fibres

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1949
1949
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1969

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Cited by 9 publications
(5 citation statements)
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“…The present theory also predicts that the form of the bond-breaking reaction should be similar to equation (14) for small stresses if OF* is the true activation energy barrier; otherwise equation (4) should hold and for small stresses the quadratic form of (5) is correct. For the bond re-formation reaction, however, difficulties immediately emerge.…”
mentioning
confidence: 61%
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“…The present theory also predicts that the form of the bond-breaking reaction should be similar to equation (14) for small stresses if OF* is the true activation energy barrier; otherwise equation (4) should hold and for small stresses the quadratic form of (5) is correct. For the bond re-formation reaction, however, difficulties immediately emerge.…”
mentioning
confidence: 61%
“…A two-state model has already been devised [2,5] ] which exhibits both nonlinear elasticity and nonlinear viscosity, but the approach was on the same lines as the Eyring model and, to bring the theory into agreement with data on keratin fibers, an additional independent Hookean spring had to be introduced in series with the two-state model. Arbitrary non-Hookean springs have also been postulated to bring the theoretical predictions of the three-element model into better agreement with experimental data [3], but there is little to be said in favor of such approaches.…”
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confidence: 99%
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“…Full theoretical discussion of the appropriate reaction rate theory, applied to the a-fJ transformation of wool fibers, from which Equation 2 is derived, is given elsewhere [2,3,7,8].…”
Section: Methodsmentioning
confidence: 99%
“…For wool fihers tested in 98%, formic acid the Hookean region disappears. The fiber is swollen cliantetrally ahout 50%, and the x-ray diffraction pattern disappears ( 17 ] . (No significant longitudinal swelling was ohserved. )…”
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confidence: 97%