-SONOS type memories have many advantages of lower operating voltages, excellent endurance and compatibility with standard metal oxide semiconductor (CMOS) technology. However, data retention and operating speed are limitations in such kind of memories. This paper reviews the evolution comes in the basic architecture of non-volatile memory devices like MNOS,SNOS and SONOS with the purpose of using high kdielectric material in each layer like tunneling layer, charge-trapping layer and blocking layer. Additionally, here we discuss different dielectric materials (HfO 2 or Al 2 O 3 /oxy-nitride gate dielectrics) and their properties like bias-temperature instabilities, radiation response and annealing characteristics used in such kind of nonvolatile semiconductor memories. This will help to understand the contributions of oxide, interface and bordertrap charges in charge buildup. This literature survey can provide insight into the fundamental charge trapping properties of high-k dielectrics and help to predict the long-term radiation response and reliability of these devices.