1996
DOI: 10.1088/0026-1394/33/4/4
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The vapour pressure of caesium between 370  C and 660  C

Abstract: We have measured the vapour pressure of caesium over the temperature range 370 C to 660 C using a pressure-controlled heat pipe. The equation log( /Pa) log( /K) 2 with the coefficients 34,573234, -4979,5799 K, -9,323 4247, 4,473 3132 10 -3 K -1 and -8,684 092 10 -7 K -2 fits the data to within ±8 mK over the entire range. In addition, the non-uniqueness of the ITS-90 appears to be less than ±1,5 mK over the same temperature range based on the data from three thermometers.

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Cited by 11 publications
(6 citation statements)
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“…This effective area value is only 3.3 ppm larger than the manufacturer-supplied value of the piston effective area from 1991, which itself carried a 13 ppm uncertainty. The acceleration due to gravity at the height of the piston gauge effective reference plane, g gravity , was re-determined in 2016 and found to be 9.8061336(10) m·s −2 , slightly larger than the value previously used for experiments performed in this laboratory [18,23,24]. Combining the new piston effective area and gravitation acceleration values results in a change of the pressure realization of less than 2 ppm relative to that used previously at NRC with the same equipment [23].…”
Section: Cryostat and Thermometrymentioning
confidence: 81%
“…This effective area value is only 3.3 ppm larger than the manufacturer-supplied value of the piston effective area from 1991, which itself carried a 13 ppm uncertainty. The acceleration due to gravity at the height of the piston gauge effective reference plane, g gravity , was re-determined in 2016 and found to be 9.8061336(10) m·s −2 , slightly larger than the value previously used for experiments performed in this laboratory [18,23,24]. Combining the new piston effective area and gravitation acceleration values results in a change of the pressure realization of less than 2 ppm relative to that used previously at NRC with the same equipment [23].…”
Section: Cryostat and Thermometrymentioning
confidence: 81%
“…A few things still remain to be tested for both Cs-PCHP and Na-PCHP, such as comparison of different wells and testing repeatability of Cs-PCHP upon furnace reheating and checking whether axial temperature homogeneity of Na-PCHP can be further improved upon reheating the chimney to melt any frozen sodium left, to name a few. And although we are still a few experiments away from the bold proposal we put forward in the abstract -namely, having a comparison apparatus in 600 K -1300 K temperature range with an exceptional temperature uniformity, stability and repeatability -the road to it is clear and lies through a better design of the PCHP itself: using Cs-PCHP with a central hole for the temperature equalizing block as in [3] for better axial and radial temperature uniformity and purchasing a one end closed Na-PCHP for better axial temperature uniformity. The new simplified gas handling system used to control the pressure in both Cs-PCHP and Na-PCHP is only the first step in the right direction.…”
Section: Nrc Pressure Controlled Heat Pipe Furnace: Future Workmentioning
confidence: 99%
“…This technique delivered outstanding temperature stability and a thermowell immersion gradient of +/-1 mK over 25 cm was realized. The system remained in operation until 1995 and was used for measuring the vapour pressure curve of Na and Cs and for producing the reference tables for platinum-gold thermocouples [40][41][42][43][44].…”
Section: National Research Council Of Canada (Nrc)mentioning
confidence: 99%