Two new types of streamer-induced electric discharges operating in a
non-uniform electric field in air at atmospheric pressure were applied to the
removal of volatile organic compounds (VOCs). The first type is a pulseless dc discharge with physical
properties corresponding to the glow discharge. The second, also supplied by a
dc high voltage of both polarities, is a spontaneously pulsing discharge
operating in the regime of the streamer-to-spark transition, the spark phase
being too short to reach local thermodynamic equilibrium conditions. Both
discharges are able to generate a non-thermal plasma, as resolved from their
rotational and vibrational temperatures.
The influences of these discharges on the removal of cyclohexanone at various
gas flow rates and concentrations (600-6000 ppm) were compared. The removal
efficiencies achieved were about 50-60%, and the energy costs were
16-100 eV/molecule at various energy densities. Special conditions where
CO2 and other gaseous products are minor and dominant products appear in
the condensed phase can be obtained, especially in the spontaneously pulsing
transition discharge.
We explain some plasmochemical processes induced by the discharges by
considering heterogeneous effects of the copper electrode surface. The role of
active nitrogen and the formation of the NCO radical are probably key factors
leading to the formation of the condensation product based on amino acids,
here produced for the first time from VOCs, as well as in the overall energy
cycle resulting in low energy costs of the process.
The small pilot-scale reactor based on the spontaneously pulsing transition
discharge has been successfully applied to the removal of cyclohexanone in the
mixture with other VOCs with no noxious gas output. This validates the
possibility of the application of such a type of reactor for larger scales.