Sizing glass fibers with silane coupling agents enhances the ad-hesion and the durability of the fiber/polymer matrix interface in composite materials. There are several tests to determine the inter-facial strength between a fiber and resin, but all of them present difficulties in interpreting the results and/or sample preparation. In this study, we observed the influence of different aminosilanes fiber coatings on the resistance of epoxy-based composite materials using a very easy fractographic test. In addition, we tried a new flu-orescence method to get information on a molecular level precisely at the interface. Strength was taken into account from two stand-points: (i) mechanical strength and (ii) the resistance to hydrolysis of the interface in oriented glass-reinforced epoxy-based composi-tes. Three silanes: γ -aminopropyltriethoxysilane, γ -Aminopropyl-methyldiethoxysilane, and γ -Aminopropyldimethylethoxysilane were used to obtain different molecular structures at the interface. It was concluded that: (i) the more accessible amine groups are, the higher the interface rigidity is; (ii) an interpenetrating network mechanism seems to be the most important for adhesion and there-fore to the interfacial strength; and (iii) the higher the degree of crosslinking in the silane coupling layer is, the higher the hydrolytic damage rate is.