We present photometric and spectroscopic observations of the Type Ia supernova SN 2009nr in UGC 8255 (z = 0.0122). Following the discovery announcement at what turned out to be ten days after peak, we detected it at V ≃ 15.7 mag in data collected by the All Sky Automated Survey (ASAS) North telescope 2 weeks prior to the peak, and then followed it up with telescopes ranging in aperture from 10-cm to 6.5-m. Using early photometric data available only from ASAS, we find that the SN is similar to the over-luminous Type Ia SN 1991T, with a peak at M V ≃ −19.6 mag, and a slow decline rate of ∆m 15 (B) ≃ 0.95 mag. The early post-maximum spectra closely resemble those of SN 1991T, while the late time spectra are more similar to those of normal Type Ia SNe. Interestingly, SN 2009nr has a projected distance of 13.0 kpc (∼ 4.3 disk scale lengths) from the nucleus of the small star-forming host galaxy UGC 8255. This indicates that the progenitor of SN 2009nr is not associated with a young stellar population, calling into question the conventional association of luminous SNe Ia with the "prompt" component directly correlated with current star formation. The pre-discovery observation of SN 2009nr using ASAS demonstrates the science utility of high cadence all sky surveys conducted using small telescopes for the discovery of nearby (d 50 Mpc) supernovae. Subject headings: supernovae: general, individual (SN 2009nr) -galaxies (UGC 8255) 1 Based on observations obtained using the 10-cm ASAS North telescope in Hawaii, the 50-cm Dedicated Monitor of Exotransit (DEMONEX) telescope at the Winer Observatory, the 2.4-m Hiltner telescope at the MDM Observatory, the 2.5-m du Pont telescope at the Las Campanas Observatory, the 3.5-m Astrophysical Research Consortium (ARC) telescope at the Apache Point Observatory, and the 6.5-m Magellan I (Baade) Telescope at the Las Campanas Observatory.