The Total Synthesis of (±)‐Camphor and (±)‐Epicamphorenone from Methylcyclopentadiene

Chang, Nein-Cben; Chiu, Chingchen S.

doi:10.1002/jccs.199300059

J Chinese Chemical Soc

1993

DOI: 10.1002/jccs.199300059

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The Total Synthesis of (±)‐Camphor and (±)‐Epicamphorenone from Methylcyclopentadiene

Nein-Cben Chang

Chingchen S. Chiu

Abstract: The total synthesis of (±)‐carnphor and (±)‐epicamphorenone from methylcyclopentadiene are described.

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1996

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Total Synthesis of (±)-2-Pupukeanone

and

Chang

1996

J. Org. Chem.

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A synthesis of (±)-2-pupukeanone (4) is described in which the pupukeanane skeleton is assembled by means of intramolecular cyclization of tosylate 11 and then the attachment of an isopropyl group at the appropriate position of the tricyclic ring system. The key intermediate 11 was constructed via a sequence begining from readily available ketone 5 and proceeding through bicyclo[3.2.1]ketone 8 by regioselective ring expansion.

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Total Synthesis of (±)-2-Pupukeanone

and

Chang

1996

J. Org. Chem.

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The Total Synthesis of (±)‐Camphor and (±)‐Epicamphorenone from Methylcyclopentadiene

Abstract: The total synthesis of (±)‐carnphor and (±)‐epicamphorenone from methylcyclopentadiene are described.

Cited by 1 publication

References 7 publications

Total Synthesis of (±)-2-Pupukeanone

Total Synthesis of (±)-2-Pupukeanone

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