In this letter, we study the two-spin-1/2 realization for the Birman-Murakami-Wenzl (B-M-W) algebra and the corresponding Yang-BaxterȒ(θ, φ) matrix. Based on the two-spin-1/2 realization for the B-M-W algebra, the three-dimensional topological space, which is spanned by topological basis, is investigated. By means of such topological basis realization, the four-dimensional Yang-BaxterȒ(θ, φ) can be reduced to Wigner D J function with J = 1. The entanglement and Berry phase in the spectral parameter space are also explored. The results show that one can obtain a set of entangled basis via Yang-BaxterȒ(θ, φ) matrix acting on the standard basis, and the entanglement degree is maximum when theȒ i (θ, φ) turns to the braiding operator.