The thermodynamic characteristics of ferrocene alkyl and acyl derivatives

Thermodynamics - Interaction Studies - Solids, Liquids and Gases

“…The absolute entropies obtained by the third thermodynamic law from the experimental data and statistical thermodynamics for some cyclic and bicyclic hydrocarbons and perfluorocarbons are listed in Table 8. The values of the absolute entropies determined by independent methods agree within errors limits from (0.1 to 1) % that proves their mutual conformity and also the reliability of the all experimental data used for computing the value of (Emel'yanenko et al, 2010); e (Karyakin, et al, 2003).…”

Thermodynamics of the Phase Equilibriums of Some Organic Compounds

“…The values of absolute entropies in homologous series of alkyl-and acyl-ferrocenes obtained in this work and available in the literature are presented in Table 9. (Emel'yanenko et al, 2010); e (Karyakin, et al, 2003). values for ferrocene, n-propyl-and iso-butylferrocene agree to within their errors that proves the reliability of these values and all the thermodynamic data used for their calculation.…”