The volcanic history of Mercury is a mirror of its thermal evolution. Volcanism is related with many geological mysteries of the planet, which have casted shadows about its origin. For example, the hypothesized graphite-rich primary crust, which was formed by the crystallization of magma ocean (Vander Kaaden & McCubbin, 2015), has been largely destroyed by subsequent volcanism and impact cratering (Klima et al., 2018). Mercury has a secondary crust that was formed by volcanism (Denevi, Ernst, et al., 2018) and its variable compositions may reflect potential lateral and/or vertical mantle heterogeneities (Charlier et al., 2013). A causal connection might exist between the hypothesized late-heavy bombardment and a possible global resurfacing by volcanism at ∼4.1 Ga, erasing most earlier geological records (Marchi et al., 2013). Young volcanic plains are relatively depleted in volatiles compared with older crust (Nittler et al., 2011), indicating that stratified abundances of volatiles might exist in the mantle if partial melting occurred at different depths; or the interior volatile budge has been substantially decreased with time (Denevi, Ernst, et al., 2018).Records of volcanism on Mercury extend from the oldest intercrater plains that were formed by effusive volcanism (Whitten et al., 2014) to the late Kuiperian-aged pyroclastic deposits (Thomas et al., 2014;