E-commerce has become an indispensable channel for network marketing in today's enterprises. Because consumers' online shopping ways will be the key factors that affect the earnings and competitiveness of enterprises. This study explores the three-faceted factors of college students' brand value, quality value and service value of online shopping brand behavior, and acquired 536 valid sample by online questionnaire, and conduct independent T test and ANOVA analysis. Results:(1) There are significant differences in "brand value" and female students are higher than male in brand value. (2) Grade four students are significant differences in "brand value" who have online shopping experience. (3) Pocket money for students, "brand value" and "quality value" are significant differences. (4) Pocket money for students range is 601-1000 of monthly, and second is 1001-1500 of monthly. (5) The college student consumer behavior decision is no significant difference between brand value and online shopping frequency.