The synthesis, structure, and catalytic properties of Cl‐substituted tridentate ONO Schiff base molybdenum(VI) complexes: Expeditious synthesis of 1,8‐dioxo‐octahydro‐xanthene derivatives
Xinran Li,
Tong Li,
Zihan Zhuo
et al.
Abstract:A family of molybdenum complexes with a general formula of [MoO2L]2 have been synthesized and fully characterized, where L is a tridentate ONO Schiff base ligand featuring a Cl substituent in different positions on the aromatic ring of salicylidene‐2‐aminophenolato backbone. The solvent molecule stabilized the monomeric structure of [MoO2LD] (D = DMF or DMSO) allowing single‐crystal X‐ray diffraction of the three new complexes. The dimeric complexes are utilized to catalyze the reaction of aldehydes/ketones wi… Show more
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