Abstract:<div>
<p>The evolution of frustrated Lewis
pair chemistry has led to significant research into the development of new
Lewis acidic boranes. Much of this has focused on modifying aryl substituents
rather than introducing heteroatoms bound to boron. We recently reported unique
Lewis acidic behaviour from bis(pentafluorophenyl)phenothiazylborane (<b>1</b>)
for the heterolytic dehydrocoupling of stannanes. In this work, we synthesize and characterize a
family of Lewis acidic aminoboranes … Show more
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