The synthesis and the spectroscopic, thermal, and structural properties of the M 2 [(fumarate)Ni(CN) 4 ]·2(1,4-Dioxane) clathrate (M = Co, Ni, Cd and Hg)

Kartal, Zeki; Yavuz, Abdülkerim

doi:10.1016/j.molstruc.2017.10.107

Cited by 9 publications

(9 citation statements)

References 51 publications

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“…The values of shifting to high frequencies in the IR and Raman spectra of the crystals were 18 and 21 cm −1 for crystal 1 and 21 and 27 cm −1 for crystal 2, respectively. Shifts to these high and low wavenumbers were also observed in studies conducted by other researchers with different ligand molecules [5][6][7].…”

Section: Vibrations Of the H 2 O Ligand And Guest Moleculessupporting

confidence: 77%

“…Furthermore, frequencies of the C ≡N group vibrations in the compounds obtained depended on the electronegativity of the transition metal atom in that compound, its environment, and the number of bonds it formed with the oxidation state. The frequency values of the C ≡N vibrations in a chemical compound depend on the type of metal, electronegativity, chemical environment, oxidation state, and number of bonds it makes [5][6][7]24,25].…”

Section: Vibrations Of the H 2 O Ligand And Guest Moleculesmentioning

confidence: 99%

“…Broad and descriptive information about Hofmann-type compounds and clathrates can be found in various studies [1][2][3][4][5][6][7].…”

Section: Introductionmentioning

confidence: 99%

“…The various structural properties of Hofmann-type complexes and clathrates can be explained by various spectroscopic methods, such as vibrational (infrared (IR) and Raman), nuclear magnetic resonance, electron spin resonance, thermal analysis, single-crystal X-ray diffraction (SC-XRD) techniques, and magnetic moment spectroscopy. The formation of Hofmann-type complexes and clathrates and/or interactions of the guest molecule with the host structure can be easily understood by means of vibrational spectroscopy [5][6][7].…”

Section: Introductionmentioning

confidence: 99%

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Synthesis of Hofmann-type Zn(H2O)2Ni(CN)4.nG (G = water and 1,4-dioxane)clathrates and the determination of their structural properties by variousspectroscopic methods

Kartal¹,

Şahın²,

Yavuz³

2019

Turk J Chem

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Two new 2-dimensional cyanide-bridged coordination polymers [Zn(H 2 O) 2 Ni(CN) 4 6(H 2 O) and Zn(H 2 O) 2 Ni(CN) 4 3(C 4 H 8 O 2) ], which were similar to Hofmann-type clathrates, were synthesized based on [Ni(CN) 4 ] 2− and Zn 2+ as building blocks. These substances were synthesized as compounds in crystalline form. Thes tructures of the crystalline compounds were characterized via their spectral analyses. General information about the structures of the newly obtained Hofmann-type clathrates was obtained from their vibration spectra by considering significant changes in the vibration peaks of the cyanide group, water ligand molecule, and guest molecules (water and 1,4-dioxane). The thermal behavior of the Hofmann-type clathrates was investigated in the range of 25-500°C. In addition, experimental data on the magnetic properties of the Hofmann-type clathrates were obtained using the Gouy method under normal conditions. Information on the properties of the structures of the Hofmann clathrates was obtained by applying the single crystal diffraction technique. The asymmetric unit of the first Hofmann-type clathrate contained 1 Zn(II) ion, 1 Ni(II) ion, 1 cyanide ligand, 1 water ligand molecule, and 2 guest water molecules. The asymmetric unit of the second Hofmann-type clathrate contained 1 Zn(II) ion, 1 Ni(II) ion, 2 cyanide ligands, 1 water ligand molecule, and 2 half guest 1,4-dioxane molecules.

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Section: Vibrations Of the H 2 O Ligand And Guest Moleculessupporting

confidence: 77%

Section: Vibrations Of the H 2 O Ligand And Guest Moleculesmentioning

confidence: 99%

“…Broad and descriptive information about Hofmann-type compounds and clathrates can be found in various studies [1][2][3][4][5][6][7].…”

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

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Synthesis of Hofmann-type Zn(H2O)2Ni(CN)4.nG (G = water and 1,4-dioxane)clathrates and the determination of their structural properties by variousspectroscopic methods

Kartal¹,

Şahın²,

Yavuz³

2019

Turk J Chem

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“…Another weak peaks at 985 cm −1 is assigned to the δ(–CN). 40–42 All peaks belong to the characteristic peaks of melamine. In the meanwhile, it is worth noting that the strength of each Raman characteristic peak was related to concentration.…”

Section: Resultsmentioning

confidence: 99%

Ultrasensitive flower-like TiO₂/Ag substrate for SERS detection of pigments and melamine

Yang

et al. 2022

RSC Adv.

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Conjugated Thermolysis of Metal-Containing Monomers: Toward Core–Shell Nanostructured Advanced Materials

Джардималиева

Uflyand

2019

J Inorg Organomet Polym

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The synthesis and the spectroscopic, thermal, and structural properties of the M 2 [(fumarate)Ni(CN) 4 ]·2(1,4-Dioxane) clathrate (M = Co, Ni, Cd and Hg)

Cited by 9 publications

References 51 publications

Synthesis of Hofmann-type Zn(H2O)2Ni(CN)4.nG (G = water and 1,4-dioxane)clathrates and the determination of their structural properties by variousspectroscopic methods

Synthesis of Hofmann-type Zn(H2O)2Ni(CN)4.nG (G = water and 1,4-dioxane)clathrates and the determination of their structural properties by variousspectroscopic methods

Ultrasensitive flower-like TiO₂/Ag substrate for SERS detection of pigments and melamine

Conjugated Thermolysis of Metal-Containing Monomers: Toward Core–Shell Nanostructured Advanced Materials

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The synthesis and the spectroscopic, thermal, and structural properties of the M 2 [(fumarate)Ni(CN) 4 ]·2(1,4-Dioxane) clathrate (M = Co, Ni, Cd and Hg)

Cited by 9 publications

References 51 publications

Synthesis of Hofmann-type Zn(H2O)2Ni(CN)4.nG (G = water and 1,4-dioxane)clathrates and the determination of their structural properties by variousspectroscopic methods

Synthesis of Hofmann-type Zn(H2O)2Ni(CN)4.nG (G = water and 1,4-dioxane)clathrates and the determination of their structural properties by variousspectroscopic methods

Ultrasensitive flower-like TiO2/Ag substrate for SERS detection of pigments and melamine

Conjugated Thermolysis of Metal-Containing Monomers: Toward Core–Shell Nanostructured Advanced Materials

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Product

Resources

About

Ultrasensitive flower-like TiO₂/Ag substrate for SERS detection of pigments and melamine