The synthesis and reactions of some N-acyl-N-aryliminium ions

Abstract

The synthesis of the N-acyl-N-aryliminium ion precursors 6 and 13 is presented and their reactions with vinyl organometallics is explored. The synthesis of N-phenyl-5-(prop-2-enyl)pyrrolidin-2-one 16 using N-acyliminium ion chemistry is described and its transformation to iodoester 21 is presented.

Succinimides: Synthesis, properties and anticonvulsant activity

“…Reakcijom N-fenilsukcinimida sa litijum-trietilborhidridom u prisustvu rastvarača THF, dobija se 5-hidroksi-N-fenilsukcinimid. Temperatura na kojoj se odvija navedena hemijska reakcija iznosi -78 °C u prisustvu inertnog gasa argona (šema 6) [21].…”