2020
DOI: 10.1134/s1063784220070178
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The Synthesis and Investigation of the Electrical Properties of Tricadmium Diarsenide with MnAs Nanogranules

Abstract: Samples of tricadmium diarsenide with MnAs nanogranules (44.7 mol % MnAs) are synthesized. The morphology of the samples is studied by X-ray phase analysis and electron microscopy. The electrical properties of tricadmium diarsenide with MnAs nanogranules are studied in a range of temperatures of 77-372 K. It is found that the voltammetric characteristics are symmetrical relative to the inversion of the voltage sign at this temperature, and their deviation from ohmicity at a certain threshold voltage and decrea… Show more

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Cited by 3 publications
(3 citation statements)
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“…2), it is characterized by a metallic type of conductivity at temperatures below critical tempera- ture T cg = 241 K of cluster glass formation (the maximum point on the curve) and by a semiconducting (thermoactivated) type of conductivity above this temperature. This kind of behavior of the electrical resistivity is consistent with the SEM image of a cleaved surface of the studied sample [12], which shows that the sample is a eutectic alloy of MnAs nanoclusters that are hardly in contact with one another and embedded in a Cd 3 As 2 semiconductor matrix. If there were any significant percolation conductivity of the Cd 3 As 2 phase, then the metallic type of conductivity would be observed for MnAs up to the Curie temperature at 325 K. As seen from Fig.…”
Section: Resultssupporting
confidence: 87%
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“…2), it is characterized by a metallic type of conductivity at temperatures below critical tempera- ture T cg = 241 K of cluster glass formation (the maximum point on the curve) and by a semiconducting (thermoactivated) type of conductivity above this temperature. This kind of behavior of the electrical resistivity is consistent with the SEM image of a cleaved surface of the studied sample [12], which shows that the sample is a eutectic alloy of MnAs nanoclusters that are hardly in contact with one another and embedded in a Cd 3 As 2 semiconductor matrix. If there were any significant percolation conductivity of the Cd 3 As 2 phase, then the metallic type of conductivity would be observed for MnAs up to the Curie temperature at 325 K. As seen from Fig.…”
Section: Resultssupporting
confidence: 87%
“…The microstructure of the sample indicates the eutectic segregation of the melt upon solidification into a system of the following two substances: Cd 3 As 2 and MnAs. Moreover, the latter is present in the form of spherical granules, which may indicate that such a segregation took place even in the melt [12].…”
Section: Resultsmentioning
confidence: 99%
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