The synthesis and characterization of solvatochromic maleimide‐fused N‐allyl‐ and N‐alkyl‐substituted 1,4‐dithiines and Diels–Alder reactions with anthracene

Abstract

A simple and facile access to new solvatochromic maleimide-fused N-allyland N-alkyl-substituted 1,4-dithiines from the corresponding N-substituted succinamic acid derivatives in one-pot with oxidation by thionyl chloride is described. The Diels-Alder reaction of these 1,4-dithiines with anthracene has been investigated. The 1,4-dithiine derivatives react smoothly with anthracene via charge-transfer complexes to form the Diels-Alder adducts in excellent yields.