The Synthesis and Characterization of Iron Sand-Based CuFe2O4 as Heavy Metal Ion Adsorbent

Abstract

This study aimed to synthesize iron sand-based Copper Ferrite (CuFe2O4) using the coprecipitation method. The iron sand was taken from South Cianjur and used as a Fe cation source to synthesize CuFe2O4 nanoparticles. Three composition variations of CuCl2.6H2O and iron sand (Fe3O4) were employed, i.e., 1:1, 1:2, and 2:1. Samples were characterized using X-Ray Diffraction (XRD), Scanning Electron Microscopy - Energy Dispersive X-Ray (SEM-EDX), and Atomic Adsorption Spectroscopy (AAS). The XRD analysis exhibits three synthesis-phase results: CuFe2O4, Fe2O3, and CuO. The produced CuFe2O4 has two crystal structures: t-CuFe2O4 in 1:2 variation and c-CuFe2O4 in variations 1:1 and 2:1. Adding Cu resulted in smaller crystal size and higher lattice parameters. SEM-EDX analysis of 1:2 sample variation showed a round-shaped particle of 102.57 nm. AAS analysis showed that the increased mole of Cu decreases the heavy metal, including Pb and Mn, adsorption capacity. The largest adsorption capacity was found in the 1:2 (60.698 mg/g).

Synergy of adsorption and solar photoreduction for removal Cr(VI) with spinel CuFe2O4

“…1) of the materials prepared by co-precipitation and sol-gel, calcined at 600°C shows that the CuFe 2 O 4 catalysts are not pure, and other crystalline structures are present regardless of the preparation method. The spinel CuFe 2 O 4 is crystallized in a cubic system with Fd-3m space group (JCPDS card 01-074-8585) [25], as evidenced by diffraction peaks corresponding to the (111), ( 220), ( 311), ( 222), ( 400), ( 422), (511), and (440) planes. The lattice parameters of samples are analogous (a s−g =8.23 Å and a co =8.34 Å) suggest that the preparation method does not in uence the cubic system of spinel structure (Table 1).…”

“…The lattice parameters of samples are analogous (a s−g =8.23 Å and a co =8.34 Å) suggest that the preparation method does not in uence the cubic system of spinel structure (Table 1). [25,29].…”