The synthesis and characterization of the octahedral Co<sup>III</sup> complex of a pyrrolopyrrolizine derivative formed with dicyanovinylene-bis-(<i>meso</i>-aryl)dipyrrin

Shin, Ji‐Young

doi:10.1039/d0ra09452h

RSC Adv.

2021

DOI: 10.1039/d0ra09452h

|View full text |Cite

The synthesis and characterization of the octahedral Co^III complex of a pyrrolopyrrolizine derivative formed with dicyanovinylene-bis-(meso-aryl)dipyrrin

Ji‐Young Shin

Abstract: A low spin state, diamagnetic, and hexa-coordinating CoIII complex of two pyrrolopyrrolizine ligands was synthesized by thermally treating the toluene solution of dicyanovinylene-bis(meso-aryl)dipyrrin and CoCl2.

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2021

Publication Types

Select...

Article1

Relationship

Self Cite0

Independent1

Authors

Journals

Cited by 1 publication

References 39 publications

(8 reference statements)

Supporting

Mentioning

Contrasting

Order By: Relevance

Exquisite chemistries of meso-pentafluorophenyl and meso-(2,6-dichlorophenyl) dipyrromethanes

Shin

Nguyen

2021

J. Porphyrins Phthalocyanines

View full text Add to dashboard Cite

meso-Aryl dipyrromethanes are important building blocks to create various practical molecules, and the electron-withdrawing effect of the meso-aryls can play an important role in improving/controlling their reactivities in further reactions: meso-Pentafluorophenyl and meso-(2,6-dichlorophenyl) substituted dipyrromethanes towards the associating dipyrrins and other derivatives have been investigated, in which coordination with different transition metals followed by the dissociation of the metal coordination by interruption of proton and halide ions have been verified. Furthermore, simple DDQ-oxidations of the dipyrromethanes have afforded DDQ-dipyrrin adducts which were delivered to distinctly advanced molecular rearrangements in the presence of acid and base. Vinylene bisdipyrrin compounds, obtained in the reactions of DDQ-dipyrrin adducts with a Lewis base triethylamine, have produced expanded porphyrinoid bis-nickel complexes during the metalation procedure with nickel acetate, while a cobalt metalation of the vinylene bisdipyrrin compounds resulted in an isolation of diamagnetic octahedral cobalt(III) complex. Moreover, meso-pentafluorophenyl and meso-(2,6-dichlorophenyl) dipyrromethanes have been useful platforms to accomplish size-controlled series of meso-aryl-substituted expanded porphyrins and easy separation/purification of selective meso-aryl expanded porphyrins, in which advanced metal complexes and various fascinating properties and reactivities admitting moderate functional molecules have arisen.

show abstract

Exquisite chemistries of meso-pentafluorophenyl and meso-(2,6-dichlorophenyl) dipyrromethanes

Shin

Nguyen

2021

J. Porphyrins Phthalocyanines

View full text Add to dashboard Cite

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

hi@scite.ai

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

The synthesis and characterization of the octahedral Co^III complex of a pyrrolopyrrolizine derivative formed with dicyanovinylene-bis-(meso-aryl)dipyrrin

Abstract: A low spin state, diamagnetic, and hexa-coordinating CoIII complex of two pyrrolopyrrolizine ligands was synthesized by thermally treating the toluene solution of dicyanovinylene-bis(meso-aryl)dipyrrin and CoCl2.

Cited by 1 publication

References 39 publications

Exquisite chemistries of meso-pentafluorophenyl and meso-(2,6-dichlorophenyl) dipyrromethanes

Exquisite chemistries of meso-pentafluorophenyl and meso-(2,6-dichlorophenyl) dipyrromethanes

Contact Info

Product

Resources

About

The synthesis and characterization of the octahedral CoIII complex of a pyrrolopyrrolizine derivative formed with dicyanovinylene-bis-(meso-aryl)dipyrrin

Abstract: A low spin state, diamagnetic, and hexa-coordinating CoIII complex of two pyrrolopyrrolizine ligands was synthesized by thermally treating the toluene solution of dicyanovinylene-bis(meso-aryl)dipyrrin and CoCl2.

Cited by 1 publication

References 39 publications

Exquisite chemistries of meso-pentafluorophenyl and meso-(2,6-dichlorophenyl) dipyrromethanes

Exquisite chemistries of meso-pentafluorophenyl and meso-(2,6-dichlorophenyl) dipyrromethanes

Contact Info

Product

Resources

About

The synthesis and characterization of the octahedral Co^III complex of a pyrrolopyrrolizine derivative formed with dicyanovinylene-bis-(meso-aryl)dipyrrin