“…These can themselves act as structure directing agents, whilst also fulfilling a charge‐balancing role. For example cationic tris(ethylenediamine) transition‐metal complexes serve to balance the charges of SbS 2 – and Sb 4 S 7 2– infinite chains in [ M (en) 3 ]Sb 2 S 4 ( M = Co, Ni, Fe), and [ M (en) 3 ]Sb 4 S 7 ( M = Co, Ni, Fe),, respectively, whilst [Ni(terpy) 2 ] 2+ (terpy = 2,2′:6′,2′′‐terpyridine) cations fulfil a similar role between Sb 10 S 17 4– layers in [Ni(terpy) 2 ] 2 [Sb 10 S 17 ] . This characteristic extends into the rare examples of three‐dimensional structures, including [Co(en) 3 ]Sb 12 S 19 , in which the three‐dimensional anionic thioantimonate framework contains [Co(en) 3 ] 2+ cations located within one‐dimensional channels and [Ni(aepa) 2 ]Sb 4 S 7 [aepa = N ‐(aminoethyl)‐1,3‐propanediamine], which contains cationic nickel complexes located above and below large Sb 14 S 14 rings …”