In this paper, based on linear matrix inequality technique, a simple controller and a compensatory controller are designed. It can track arbitrary fixed points and any periodic orbits. In addition, a synchronization control method via Chebyshev neural network with external disturbances is proposed. An adaptive controller is given. The Chebyshev neural network is used to approximate the uncertain nonlinear function and the adaptive law is used to adjust the corresponding parameters in the system. Taking a 4D memristive chaotic system as examples, the results are in consistent with the simulations. From a framework and control theoretical point of view, the proposed synchronization approach via compensation controller and Chebyshev neural network is firstly presented. From an application point of view, the proposed scheme can simplify the complexity of controller design. It is promising in many applications for mem-systems as secure communications and neural networks.