1998
DOI: 10.1016/s0927-7757(97)00086-1
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The surface chemistry of hybrid nanometer-sized particles I. Photochemical deposition of gold on ultrafine TiO2 particles

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Cited by 128 publications
(65 citation statements)
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“…Electron and hole pairs are generated in the CNDs upon UV excitation (reaction 1) [35,36]. The photogenerated electrons reduced the surrounding AuCl 4 − (reaction 2), while the holes were scavenged by the alcohols (reactions 6) [37]. Au 0 atoms are generated after the fast disproportionation of Au 2 + (reaction 3) and the disproportionation of Au + and Au 2 + (reaction 4) [38].…”
Section: Methodsmentioning
confidence: 99%
“…Electron and hole pairs are generated in the CNDs upon UV excitation (reaction 1) [35,36]. The photogenerated electrons reduced the surrounding AuCl 4 − (reaction 2), while the holes were scavenged by the alcohols (reactions 6) [37]. Au 0 atoms are generated after the fast disproportionation of Au 2 + (reaction 3) and the disproportionation of Au + and Au 2 + (reaction 4) [38].…”
Section: Methodsmentioning
confidence: 99%
“…Wet chemical processes involving reduction or thermal decomposition of metal salts are the most used synthesis techniques. [96] Wide variations of wet chemical processes include: polyol methods, [97] photochemical deposition, [98] electroless plating, [99] solvothermal, [100] hydrothermal, [101] sol-gel, [39] ion-implantation, [102] epitaxial growth, [103] etc. Vapour-gas phase processes, such as flame aerosol [104] and plasma-assisted deposition [105] are also commonly used.…”
Section: Metal-metal Nanohybrids (Mmnhs)mentioning
confidence: 99%
“…One is to modify TiO 2 by surface deposition of noble metal clusters. 12 The second is to couple TiO 2 with other semiconductors which can trap the photogenerated e − or h + . 13 The third alternative way is to introduce defects into the TiO 2 lattice by doping with transition metal ions, e.g.…”
Section: Introductionmentioning
confidence: 99%