To improve the combination of graphite and copper, the
friction
and wear of a graphite/copper composite with a high content of graphite
(50 wt %), copper-coated graphite were used to modify it. To observe
the distribution law of each phase in the material and the change
of composite surface structure after the friction and wear experiment,
scanning electron microscopy (SEM) and transmission electron microscopy
(TEM) were used to characterize the micro-structure, friction film,
debris, and friction cross section of the composites. The results
show that the large particle size of copper-coated graphite is anisotropic
in the material, which helps to form a friction film with a high graphite
content on the contact surface. TEM images of the friction film and
debris directly reflect the structure changes of graphite and copper
during friction; under normal load and shear force, interlamellar
detachment and interlamellar fracture of graphite occur, and its edge
is folded and crimped, resulting in the loss of an ordered state in
some regions, which results in the instability of crystal lattice
and the transition from an ordered to disordered state of graphite,
resulting in the (002) halo ring in FFT results. Severe plastic deformation
and oxidation reactions occur in copper, and copper oxides are formed,
forming a high-strength and smooth oxide film in the metal-rich area
and improving the wear resistance of the material. TEM images of the
friction section directly show that an inverted triangular deformation
zone is formed on the surface of the sample after friction and wear
experiments. The edge of the deformation zone is stepped, consisting
of a drag zone and an accumulation zone, and the surface of the contact
zone is covered by a carbon film.