1996
DOI: 10.1070/rc1996v065n10abeh000328
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The structure and properties of block poly(vinylidene fluoride) and systems based on it

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Cited by 104 publications
(119 citation statements)
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“…22 It is known that for the latter the conformation of plain zigzag is typical, with dipolar moment perpendicular to the macromolecular axis, while the chains in a-phase have TGTG À conformation, which have nonzero component of the dipole moment m jj directed along the chain axis. 8 The axes are oriented practically perfectly along the drawing axis in textured PVDF films with a-phase macromolecular crystals. In these films, if the external electric field is applied along and then across the drawing axis, the contribution of m jj to the mechanism of a c -relaxation can be revealed.…”
Section: Introductionmentioning
confidence: 99%
See 1 more Smart Citation
“…22 It is known that for the latter the conformation of plain zigzag is typical, with dipolar moment perpendicular to the macromolecular axis, while the chains in a-phase have TGTG À conformation, which have nonzero component of the dipole moment m jj directed along the chain axis. 8 The axes are oriented practically perfectly along the drawing axis in textured PVDF films with a-phase macromolecular crystals. In these films, if the external electric field is applied along and then across the drawing axis, the contribution of m jj to the mechanism of a c -relaxation can be revealed.…”
Section: Introductionmentioning
confidence: 99%
“…As the basic component of a copolymer is PVDF with strongly pronounced polymorphism, 4,8 it is worth to discuss relaxation processes in this polymer. They were studied both experimentally and by computer modeling.…”
Section: Introductionmentioning
confidence: 99%
“…1, the lamellae are embedded in amorphous interlayers. Previous x-ray and infrared-spectroscopy studies have demonstrated that, in addition to the T conformation, chains occurring in a mixed conformation, TG (gauche) or TG − , are also present in P (VDF-TrFE) [32]. They should be located in the amorphous interlayers.…”
mentioning
confidence: 99%
“…Weak absorption bands at 552 cm -1 from CF 2 bending and 813 cm -1 from CH 2 rocking vibrations are generally assigned to the c-polymorph phase. [10,24] The 1113 cm -1 relatively intense peak in films deposited by continuous CVP process is assigned to the c-phase. [27] In pulsed deposited CPV films, the 1113 cm -1 peak is absent and other c-phase [28]…”
Section: Molecular Structure Of Filmsmentioning
confidence: 99%
“…[10][11][12] Most studies done on freestanding, ∼1-5 lm thick films formed by melt-extrusion [13] and solution-casting, [14] establish the effects of thermal, mechanical (stretching), and polar treatments on changes in crystallinity and orientation which are essential to realize their unique piezo-and ferroelectric properties. [10][11][12]15] For emerging microelectronics applications, growth techniques to form ferroelectric PVDF thin films in the nanometer thickness range are more relevant, but are not possible by these techniques. Furthermore, the ability of the deposition technique for integration of PVDF films in Si-device structures with sub-micrometer surface features is also an important consideration.…”
Section: Introductionmentioning
confidence: 99%