The Structure and Dipole Moment of SO2 from Microwave Spectra

Crable, George F.; Smith, William V.

doi:10.1063/1.1748255

Cited by 36 publications

(12 citation statements)

References 6 publications

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“…The most probable space groups are therefore Aba and Abam. The latter is compatible only with a linear molecule; electron-diffraction, dipole-moment and spectroscopic measurements indicate that sulfur dioxide is non-linear (Cross & Brockway, 1935;Schomaker & Stevenson, 1940;Crable & Smith, 1951). The non-linearity of the molecule can also be readily demonstrated from X-ray diffraction data.…”

Section: Unit Cell and Space ~Roupmentioning

confidence: 51%

The crystal structure of sulfur dioxide

Post¹,

Schwartz²,

Fankuchen³

1952

Acta Crystallogr

121

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Section: Unit Cell and Space ~Roupmentioning

confidence: 51%

The crystal structure of sulfur dioxide

Post¹,

Schwartz²,

Fankuchen³

1952

Acta Crystallogr

121

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“…For sulfur dioxide gas, the product of the moments of inertia was taken as the average of th e microwave measurements of Dailey, G olden, and liVilson [9], who obtained 106.403 X 10-117 g3cm6, Sirvetz [10], 107.007 X 10-117 g3cm6, and Crable and Smith [11], 106.996 X 10-117 g3cm6. This product of the moments of inertia, 106.80 X lO -117 g3cm6, and the vibrational frequencies given by Herzberg [12] were used in a rigid rotator-harmonic oscillator calculation.…”

Section: Calculation Of the Thermodynamic Functionsmentioning

confidence: 99%

Thermodynamics of some simple sulfur-containing molecules

Evans¹,

Wagman²

1952

J. RES. NATL. BUR. STAN.

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The t hermodynamic functions ( F o-f1~) / T, ( HO -H~) / T, So ( Ho-Tl~) , and C; are calculated to high temperatures for gaseous sulfur (mon atomic and di ato mic) , sulfur monoxide, s ulfur dioxide, sulfur trioxide, and hydroge n sulfide from molecular and spectroscopic data. Values of the heats of formation of the various ato mic and molec uiar species are selected from published experimental data, and certain industrially importa ntequ ilibria are calculated.

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“…infrarouge [1], [2], [3], et son spectre de microondes [4], [5], [6]. ' Les recherches de microondes ont déterminé l'angle 0-S-0 et la distance 0-S comme étant respectivement de [3], Murai [4] et Craig [5].…”

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“…' Les recherches de microondes ont déterminé l'angle 0-S-0 et la distance 0-S comme étant respectivement de [3], Murai [4] et Craig [5]. Une première tentative pour tenir compte aussi des élec-trons a été faite par Altmann [6].…”

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