Assessment of electrical network vulnerability based on complex network theory (CNT) has attracted increasing attention. However, CNT focuses on analyzing the structural vulnerability and has significant limitations regarding operational vulnerability. To address the lack of a comprehensive CNT-based framework to assess operational vulnerability, a temporal-spatial correlation graph (TSCG) that considers the topological, physical, and operational characteristics of electrical networks is proposed. To better assess vulnerability, two metrics, i.e., impact ability and susceptibility of branches, based on symmetric entropy from the load redistribution mechanism of electrical networks and their corresponding TSCGs are proposed. Applications to IEEE 39-bus system, IEEE 118-bus system, and French grid demonstrate that the proposed TSCGs have distinctive features that can intuitively and simply reveal the features of impact ability and susceptibility in CNT.