Abstract:The problem of the orientational disorder in mixed stack charge transfer crystals has been addressed. X-ray diffraction data in the HT phase of A-TCNB are reported. They were analysed using conventional structure-refinement procedures and utilizing symmetry-adapted functions. For the HT phase, the orientational probability function allowed us to characterize as dynamic the disorder of the anthracene molecules. The soft mode was measured by Raman and coherent neutron scattering. Measurement by Brillouin scatter… Show more
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