The structural determination and skeletal ring modes of tetrahydropyran

Gruet, Sébastien; Pirali, Olivier; Steber, Amanda L.; Schnell, Melanie

doi:10.1039/c8cp06204h

Phys. Chem. Chem. Phys.

2019

DOI: 10.1039/c8cp06204h

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The structural determination and skeletal ring modes of tetrahydropyran

Sébastien Gruet

Olivier Pirali

Amanda L. Steber

et al.

Abstract: A high-resolution molecular spectroscopy study was carried out on the cyclic ether tetrahydropyran (THP), one of the smallest molecules composed of a pyranose ring.

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Cited by 4 publications

References 35 publications

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Water‐Lean Inner Helmholtz Plane Enabled by Tetrahydropyran for Highly Reversible Zinc Metal Anode

Fu,

Liu,

Xie

et al. 2024

Adv Funct Materials

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The reversibility and stability of zinc (Zn) metal anode are closely related to inner Helmholtz plane (IHP) chemistry. The H2O‐rich IHP raises severe parasitic reactions and irregular Zn deposition, impeding the practical utility of Zn anode in aqueous Zn‐ion batteries (AZIBs). In this study, tetrahydropyran (THP), a five‐carbon heterocyclic ether with permanent dipole moment and hydrophobic characteristic, is introduced as a self‐adsorptive additive to reshape the IHP. It squeezes out partial H2O molecules and forms a H2O‐lean IHP, benefitting for alleviating active H2O decomposition and improving the stability of Zn anode. Moreover, the adsorbed THP induces the preferential nucleation of Zn (002) plane, facilitating dendrite‐free growth and improving the reversibility of Zn anode. Consequently, the Zn||Zn symmetric cell enables to cycle over 3600 h at 5 mA cm−2@ 1 mAh cm−2. The Zn||Cu half‐cell can stably cycle over 400 cycles with 99.9% coulombic efficiency even under harsh test conditions (10 mA cm−2@5 mAh cm−2) with 30 µm Zn foil. The Zn||NH4V4O10 full cell maintains 92.6% capacity retention after 800 cycles at 1 A g−1 and the Zn||I2 full cell enables to perform steadily over 10000 cycles with a capacity decay rate of merely 0.003% per cycle at 5 C.

show abstract

Water‐Lean Inner Helmholtz Plane Enabled by Tetrahydropyran for Highly Reversible Zinc Metal Anode

Fu,

Liu,

Xie

et al. 2024

Adv Funct Materials

View full text Add to dashboard Cite

show abstract

Transmembrane penetration mechanism of cyclic pollutants inspected by molecular dynamics and metadynamics: the case of morpholine, phenol, 1,4-dioxane and oxane

Rózsa

Szőri-Dorogházi

Viskolcz

et al. 2021

Phys. Chem. Chem. Phys.

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Structures and hydrogen bonding of 1,7-dioxaspiro[5.5]undecane and its hydrates

Wei

et al. 2021

Phys. Chem. Chem. Phys.

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The structural determination and skeletal ring modes of tetrahydropyran

Abstract: A high-resolution molecular spectroscopy study was carried out on the cyclic ether tetrahydropyran (THP), one of the smallest molecules composed of a pyranose ring.

Cited by 4 publications

References 35 publications

Water‐Lean Inner Helmholtz Plane Enabled by Tetrahydropyran for Highly Reversible Zinc Metal Anode

Water‐Lean Inner Helmholtz Plane Enabled by Tetrahydropyran for Highly Reversible Zinc Metal Anode

Transmembrane penetration mechanism of cyclic pollutants inspected by molecular dynamics and metadynamics: the case of morpholine, phenol, 1,4-dioxane and oxane

Structures and hydrogen bonding of 1,7-dioxaspiro[5.5]undecane and its hydrates

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