The story of conducting polymers  for plastic electronics

Moliton, André

doi:10.1002/pi.5772

Cited by 5 publications

(3 citation statements)

References 45 publications

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“…Semiconductive polymers play a key role in the new era of "plastic electronics". [1] Due to their electrochemical, photophysical, mechanical and optical properties, conductive polymers have been successfully established in electronic devices used in xerography, photovoltaic cells, light-emitting diodes, and organic field-effect transistors. [2,3,4,5] Therefore, semiconductive polymers are promising materials to replace the standard metals and metalloids paving the way to a modern resource-saving industry.…”

Section: Introductionmentioning

confidence: 99%

Synthesis and Photophysical Properties of Luminescent Phenothiazinyl Merocyanine Substituted Polyacetylenes

Pisetsky,

Budny,

Müller

2023

Angew Chem Int Ed

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A new generation of soluble phenothiazinyl merocyanine substituted polyacetylenes can be readily synthesized by rhodium‐catalyzed polymerization of the corresponding 3‐ethynyl phenothiazines, accessible by Sonogashira coupling and Knoevenagel condensation. UV/Vis and fluorescence spectroscopy of 7‐acceptor‐substituted phenothiazinyl polyacetylenes reveal that these polyacetylenes with conjugatively ligated merocyanines are luminescent in solution with positive emission solvatochromism and, in some cases, with distinct solid‐state luminescence.

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Section: Introductionmentioning

confidence: 99%

Synthesis and Photophysical Properties of Luminescent Phenothiazinyl Merocyanine Substituted Polyacetylenes

Pisetsky,

Budny,

Müller

2023

Angew Chem Int Ed

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“…Halbleitende Polymere spielen eine Schlüsselrolle im Zeitalter der "Organischen Elektronik". [1] Aufgrund ihrer elektrochemischen, photophysikalischen, mechanischen und optischen Eigenschaften konnten leitfähige Polymere erfolgreich in Bauelementen etabliert werden und Anwendung in der Xerographie, in Solarzellen, in lichtemittierenden Dioden sowie in organischen Feldeffekttransistoren finden. [2][3][4][5] Daher sind halbleitende Polymere Materialien, die herkömmliche Metalle und Halbmetalle ersetzen und den Weg zu einer modernen ressourcenschonenden Industrie ebnen können.…”

Section: Introductionunclassified

Synthese und photophysikalische Eigenschaften von lumineszenten Phenothiazinyl‐Merocyanin‐substituierten Polyacetylenen

Pisetsky,

Budny,

Müller

2023

Angewandte Chemie

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Eine neue Generation löslicher Phenothiazinyl‐Merocyanin‐substituierter Polyacetylene wurde mittels Rhodium‐katalyisierter Polymerisation der entsprechenden 3‐Ethinyl‐Phenothiazine dargestellt. Die Monomere sind über Sonogashira‐Kupplung und Knoevenagel‐Kondensation zugänglich. UV/Vis‐ und fluoreszenzspektroskopische Untersuchungen der 7‐Acceptor‐substituierten Phenothiazinyl‐Polyacetylene zeigen, dass diese Polymere mit konjugiert verknüpften Merocyaninen in Lösung mit positiver Emissionssolvatochromie lumineszieren und in bestimmten Fällen eine ausgeprägte Festkörperlumineszenz aufweisen.

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“…1-3 Polyacetylene, polypyrrole, polyaniline and polythiophene are the most common intrinsically conductive polymers applied in wearable textiles due to their biocompatibility, easier surface modification, and large surface area. 4 Among them, polyaniline has drawn enormous attention from researchers and industry people because of its low cost, simple fabrication, high conductivity and better chemical stability compared to other conductive polymers. 5,6 Polyaniline has been widely used in solar cells, 7 chemical sensors, 8 electromechanical devices, 9 electromagnetic shielding devices, 10 filtration 11 and antistatic materials 12 due to its electrochemical activity and electrochromic properties.…”

Section: Introductionmentioning

confidence: 99%

Fabrication and properties of polyaniline/ramie composite fabric based on in situ polymerization

Chowdhury

Jin

et al. 2021

Polymers and Polymer Composites

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Polyaniline (PANI) is one of the most important conducting polymer and has been widely used in various fields for its tunable electrical conductivity. In this manuscript, conductive polyaniline/ramie fabrics were developed by in situ polymerization and characterized. The effect of aniline content, polyetherimide (PEI) pretreatment, padding and the color depth (K/S value) on electrical resistivity was analyzed. The result showed that electrical conductivity was increased with the increase of aniline (ANI) contents. PEI pretreatment and padding method improved the conductivity of the fabric significantly. The result of K/S value was reversely consistent with the conductivity. Both scanning electron microscope (SEM) and Fourier transform infrared spectroscopy (FTIR) analysis confirmed that polyaniline particles were successfully deposited on the surface of the ramie fabrics. Thermal degradation (TG) measurement showed that polyaniline (PANI) polymerization decreased the onset decomposition temperature. Mechanical measurement showed that pretreatment process reduced the tensile strength of conductive ramie fabrics by 30%. K/S value in full range showed that the color of PANI/ramie fabric was sensible to pH value. Contact angle (CA) measurement disclosed the conductive PANI/ramie fabric was hydrophobic and this hydrophobicity was stable to the change of pH value. The obtained PANI/ramie fabrics can be used as potential conductive multifunctional textiles.

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The story of conducting polymers for plastic electronics

Cited by 5 publications

References 45 publications

Synthesis and Photophysical Properties of Luminescent Phenothiazinyl Merocyanine Substituted Polyacetylenes

Synthesis and Photophysical Properties of Luminescent Phenothiazinyl Merocyanine Substituted Polyacetylenes

Synthese und photophysikalische Eigenschaften von lumineszenten Phenothiazinyl‐Merocyanin‐substituierten Polyacetylenen

Fabrication and properties of polyaniline/ramie composite fabric based on in situ polymerization

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