The stereochemistry of fragmentation products formed in the lead tetraacetate and related oxidations of alcohols. Part. I. β‐fragmentation of cis‐and trans‐4‐t‐Butylcyclohexanemethanol
Abstract:The stereochemistry of β‐fragmentation products formed in the oxidation of cis‐and trans‐4‐t‐butylcyclohexaanemethanol with lead tetraacetate and with lead tetraacetate‐metal chloride combinations, under various reaction conditions, has been investigated, and the results compared with those obtained, under similar conditions, in the oxidative decarboxylation of cis‐and trans‐4‐t‐butylcyclohexanecarboxylic acid with the same reagents. It was found that all four substrates afford, under comparable conditions, id… Show more
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