Abstract. A number of integral Hopf algebras have been studied that have, as their underlying modules, the free Z-module generated by finite words in a certain alphabet. For example, the tensor algebra, the rings of quasisymmetric functions and of noncommutative symmetric functions, the Solomon descent algebra, the MalvenutoReutenauer algebra and the homology and cohomology of CP ∞ are all of this type. Some of these are known to be isomorphic or dual to each other, some are known only to be rationally isomorphic, some have been stated in the literature to be isomorphic when they are only rationally isomorphic.This paper is, in part, an attempt to find order in this chaos of word Hopf algebras. We consider three multiplications on such modules, and their dual comultiplications, and clarify which of these operations can be combined to obtain Hopf structures. We discuss when the results are isomorphic, integrally or rationally, and study the resulting structures. We are not attempting a classification of Hopf algebras of words, merely an organization of some of the Hopf algebras of this type that have been studied in the literature.2000 Mathematics Subject Classification. 16W30, 57T05, 05E05, 55S10.1. The basic set-up. Given a set S, thought of as a collection of letters, we can form the free monoid WS consisting of finite words in S, the monoidal operation being composition. Here it is assumed that a word has positive length; we let WS denote the unital monoid obtained by adjoining to WS a unique 'empty word' of length 0 (which will give the unit and counit in the algebras and coalgebras we consider). Then we can take the free abelian groups ZWS and ZWS generated by these monoids, the elements of these groups being Z-linear combinations of words. Of course ZWS = ZWS ⊕ Z.We shall restrict ourselves to the graded setting, and so we assume that S is given a grading in which every element has positive degree and only finitely many elements have the same degree. The degree of a word is defined to be the sum of the degrees of the letters that form it and so ZWS becomes graded and of finite type; i.e., the degree n part, ZWS n , of ZWS, has finite rank. We can then form the graded dual (ZWS) * = n (ZWS n ) * , and when we speak of duality we shall always mean this graded duality. Each ZWS n has an obvious basis consisting of the words of degree n, and we give (ZWS n ) * the dual basis, collating all of these to provide a basis for (ZWS) * . Of course, the elements of this dual basis are indexed by words, giving a Z-linear isomorphism between ZWS and (ZWS) * . A Hopf algebra structure consists of a multiplication on ZWS, and a compatible comultiplication on ZWS, the antipode being given automatically since ZWS is graded and connected. Moreover, a comultiplication can be considered as the dual of a multiplication on (ZWS) * which, by at https://www.cambridge.org/core/terms. https://doi